Quantum‐Chemical Insight into Self‐Organization of Complex Molecules from Acetylene and Anilines Catalyzed by Superbase KOH/DMSO: One‐Pot Cascade Assembly of 1,3‐Bis(arylamines)

The method of one-pot assembly 1-Acetyl-1,3-bis(2-chloroaniline) is attractive from the point view green chemistry principles: pot-, atom-, step-economical, resource, and energy-saving procedures using available starting materials simple catalytic systems. mechanisms reactions that proceed sequentially in a superbasic KOH/DMSO medium form unique cascade 1,3-diamine 2-chloroaniline acetylene are studied quantum-chemically. More information can be found Research Article by Nadezhda M. Vitkovskaya et al.